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ɉԤ (S
6+
–
O
2
Ǧ) > ɉԤ (S
4+
–
O
2
Ǧ), ԧɣɬɤɟɧɿ
q (S
6+
) > q (S
4+
)
r (S
6+
) < r (S
4+
)
ɋɨԙɞɵԕɬɚɧ, Į (ɇ
2
SɈ
4
) >
Į (ɇ
2
SɈ
3
), ɫԥɣɤɟɫɿɧɲɟ,
ɌȻ (ɇ
2
SɈ
4
) > ɌȻ (ɇ
2
SɈ
3
), ɹԑɧɢ
Ɍ
ɵɞɵɪ.
(
ɇ
2
SɈ
4
) > Ɍ
ɵɞɵɪ
.
(ɇ
2
SɈ
3
).
ɇ
2
SɈ
4
SɈ
3
+ ɇ
2
Ɉ (Ɍ
ɵɞɵɪ
.
= 330
0
ɋ
);
ɇ
2
SɈ
3
SɈ
2
+ ɇ
2
Ɉ (Ɍ
ɵɞɵɪ
.
= 20
0
ɋ
).
3-
ɦɵɫɚɥ:
(ɇɋ1) ɠԥɧɟ Ɍɉ (ɇBr) ԕɵɲԕɵɥɞɚɪɵɧɵԙ ɬɟɪɦɢɹɥɵԕ
ɛɟɪɿɤɬɿɝɿɧ (ɌȻ) ɫɚɥɵɫɬɵɪɵԙɵɡ.
ɉԤ (ɇ
1+
–
Cl
1
Ǧ) > ɉԤ (ɇ
1+
–
Br
1
Ǧ
)
q [(Cl
1
Ǧ
)] = q [(Br
1
Ǧ
)]
r (Cl
1
Ǧ
) < r (Br
1
Ǧ
)
ɋɨԙɞɵԕɬɚɧ, Į
(
ɇɋ
1) <
Į
(
ɇ
Br),
ɫԥɣɤɟɫɿɧɲɟ
ɌȻ (ɇCl) > ɌȻ (ɇBr), ɹԑɧɢ
Ɍ
ɵɞɵɪ.
( ɇCl) > Ɍ
ɵɞɵɪ.
(
ɇBr)
2ɇɋ1
ɇ
2
+ ɋ1
2
(Ɍ
ɵɞɵɪ
.
= 1500
0
ɋ
)
2ɇBr
ɇ
2
+ Br
2
(Ɍ
ɵɞɵɪ
.
= 1000
0
ɋ
)
ɌΡɡɞɚɪɞɵΝ ɬɟɪɦɢɹɥɵΙ ɛɟɪɿɤɬɿɝɿɧ
ɫɚɥɵɫɬɵɪɭԑɚ ɛɨɥɚɞɵ:
ɟɝɟɪ ɬԝɡɞɚɪ ɛɿɪɞɟɣ ɤɚɬɢɨɧɞɚɪɞɚɧ ɧɟɦɟɫɟ ɛɿɪɞɟɣ ɚɧɢɨɧɞɚɪɞɚɧ
ɬԛɡɿɥɝɟɧ ɠɚԑɞɚɣɞɚ:
¾
ɛɿɪɞɟɣ ɤɚɬɢɨɧɞɚɪɦɟɧ, ɛɿɪɚΙ ΩɪɬΟɪɥɿ ɚɧɢɨɧɞɚɪɦɟɧ
ɬԛɡɿɥɝɟɧ ɬԝɡɞɚɪ: ɬԝɡ ɬԛɡɟɬɿɧ ԕɵɲԕɵɥ ɤԛɲɬɿ ɛɨɥԑɚɧ ɫɚɣɵɧ, ɨɫɵ
ɬԝɡɞɵԙ ɬɟɪɦɢɹɥɵԕ ɛɟɪɿɤɬɿɝɿ ɠɨԑɚɪɵ ɛɨɥɚɞɵ;
¾
ΩɪɬΟɪɥɿ ɤɚɬɢɨɧɞɚɪɦɟɧ, ɛɿɪɚΙ ɛɿɪɞɟɣ ɚɧɢɨɧɞɚɪɦɟɧ
ɬԛɡɿɥɝɟɧ ɬԝɡɞɚɪ: ɬԝɡ ɬԛɡɟɬɿɧ ɧɟɝɿɡ ɤԛɲɬɿ ɛɨɥԑɚɧ ɫɚɣɵɧ, ɨɫɵ
ɬԝɡɞɵԙ ɬɟɪɦɢɹɥɵԕ ɛɟɪɿɤɬɿɝɿ ɠɨԑɚɪɵ ɛɨɥɚɞɵ.
Ɍԝɡɞɚɪɞɵԙ ɬɟɪɦɢɹɥɵԕ ɛɟɪɿɤɬɿɝɿɧ ɫɚɥɵɫɬɵɪɭ ԛɲɿɧ, ɛɿɪɿɧɲɿ
ɠɚԑɞɚɣɞɚ ɨɫɵ ɬԝɡɞɚɪɞɵ ɬԛɡɟɬɿɧ ԕɵɲԕɵɥɞɚɪɞɵԙ ɤԛɲɬɟɪɿɧ, ɚɥ
ɟɤɿɧɲɿ ɠɚԑɞɚɣɞɚ, ɧɟɝɿɡɞɿɤ ɤԛɲɬɟɪɿɧ ɫɚɥɵɫɬɵɪɚɞɵ.
4-
ɦɵɫɚɥ:
ɌȻ (CaCO
3
) ɠԥɧɟ ɌȻ (CaSO
4
) ɬԝɡɞɚɪɵɧ ɫɚɥɵɫɬɵ
-
ɪɵԙɵɡ.
Ȼԝɥ ɬԝɡɞɚɪ ɛɿɪɞɟɣ ɤɚɬɢɨɧɞɚɪɞɚɧ, ɛɿɪɚԕ ԥɪɬԛɪɥɿ ɚɧɢɨɧɞɚɪɞɚɧ
ɬԛɡɿɥɝɟɧ, ɫɨɧɞɵԕɬɚɧ ɚɥɞɵɦɟɧ ɇ
2
CO
3
ɧɟɦɟɫɟ ɇ
2
SO
4
ɨɤɫɨ
-
ԕɵɲԕɵɥɵɧɵԙ ԕɚɣɫɵɫɵ ɤԛɲɬɿ ɟɤɟɧɿɧ ɚɧɵԕɬɚɭ ɤɟɪɟɤ:
ɉԤ (ɋ
4+
–
Ɉ
2
Ǧ) < ɉԤ
(S
6+
–
Ɉ
2
Ǧ), ԧɣɬɤɟɧɿ
5
–
3/129-15