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2NɚNɈ
2
+ Ɉ
2
o
2NɚNɈ
3
Nɚ
2
S + ȼr
2
o
2Naȼr + S
p
5ɄClO
3
+ 6Ɋ
o
5Ʉɋ1 + 3Ɋ
2
Ɉ
5
ȼɚSɈ
4
+ 2ɋ
o
ȼɚS + ɋɈ
2
n
Ʉ
2
ɋɝ
2
Ɉ
7
+ S
o
ɋɝ
2
Ɉ
3
+ Ʉ
2
SɈ
4
2KI + ȼr
2
o
2Ʉȼr + I
2
2Ʉȼr + ɋ1
2
o
2Ʉɋ1 + ȼr
2
2Nɚȱ + ɋ1
2
o
2Nɚɋ1 + ȱ
2
p
x
ɦɟɬɚɥɞɚɪ ɛɟɣɦɟɬɚɥɞɚɪɦɟɧ Ωɪɟɤɟɬɬɟɫɭɿ:
ɦɟɬɚɥɞɚɪ
ɛɟɣɦɟɬɚɥɞɚɪɦɟɧ ɠԥɧɟ ɛɟɣɦɟɬɚɥɞɚɪ ɛɿɪ
-
ɛɿɪɿɦɟɧ ԥɪɟɤɟɬɟɫɿɩ,
ɛɢɧɚɪɥɵ ԕɨɫɵɥɵɫɬɚɪ ɬԛɡɟɞɿ (ɦɟɬɚɥɞɚɪɞɵԙ ԕɚɫɢɟɬɬɟɪɿɧ ԕɚɪɚԙɵɡ).
2Cl
2
n
+ 2P (ɚɡ)
o
2PCl
3
5Cl
2
n
+ 2P (ɚɪɬ.)
o
2PCl
5
4P
+ 3O
2
n
(ɚɡ)
o
2P
2
O
3
4P
+ 5O
2
n
(ɚɪɬ.)
o
2P
2
O
5
Cl
2
n
+ H
2
n
o
2HCl
n
F
2
n
+ H
2
n o
2HF
n
2F
2
+ Si
o
2SiF
4
2F
2
+ S
o
SF
6
2ɇ
2
n
+ O
2
n o
2H
2
O
n
H
2
n
+ S
o
H
2
S
I
2
+ H
2
n o
2HI 2P
+ 3S (ɚɡ)
o
P
2
S
3
2S + C
o
CS
2
2P
+ 5S (ɚɪɬ.)
o
P
2
S
5
N
2
n
+ O
2
n o
2NO (T > 2000
0
C) Ƚ
2
n
+ O
2
n
z
(Ƚ - ɋ1, ȼr, I )
13.4 ɩˆ˓ʶʺˑʹ˲ ˫ˏʺːʺˑ˘˘ʺ˕ʹ˲˒
˟ˆ˄ˆ˓ˏ˓ʶˆˮˏ˩ˌ ːˬˑ˲
Ȼɟɥɝɿɥɿ ɚɤɚɞɟɦɢɤ Ⱥ.ɇ. ɇɟɫɦɟɹɧɨɜɬɵԙ ɫԧɡɿ ɛɨɣɵɧɲɚ «
ɌɚΕɚɦ –
ɛΡɥ ɦɵΝɞɚΕɚɧ ΙΡɪɚɦ ɛΫɥɿɤɬɟɪɞɟɧ ɬΡɪɚɬɵɧ, ɚɞɚɦ ɚΕɡɚɫɵɧɚ
ɮɢɡɢɨɥɨɝɢɹɥɵΙ Ωɫɟɪ ɟɬɭɝɟ Ιɚɛɿɥɟɬɬɿ ɤΟɪɞɟɥɿ ɯɢɦɢɹɥɵΙ
ɤɨɦɩɥɟɤɫ
».
Ɍɚɦɚԕɬɚɧɭɞɵԙ ɛɢɨɯɢɦɢɹɫɵ ɬԝɪԑɵɫɵɧɚɧ ɬɚԑɚɦɞɵԕ ɡɚɬɬɚɪɞɵ
ɲɚɪɬɬɵ ɬԛɪɞɟ ɧɟɝɿɡɝɿ ɟɤɿ ɤɥɚɫԕɚ ɛԧɥɭɝɟ ɛɨɥɚɞɵ: ɛԝɥ
ɦɚɤɪɨɧɭɬɪɢɟɧɬɬɟɪ
ɞɟɩ ɚɬɚɥɚɬɵɧ ɬɚԑɚɦɞɵԕ ɡɚɬɬɚɪɞɵԙ ɛɚɫɬɵ
ɤɥɚɫɵ, ɨɥɚɪ ɚԕɭɵɡɞɚɪ, ɦɚɣɥɚɪ ɦɟɧ ɤԧɦɿɪɫɭɥɚɪ ɠԥɧɟ
ɦɢɤɪɨ-
ɧɭɬɪɢɟɧɬɬɟɪ
ɤɥɚɫɵ, ɨԑɚɧ ɛɿɪɧɟɲɟ ɠԛɡɞɟɝɟɧ ɬɚԑɚɦ ɤɨɦɩɨ-
ɧɟɧɬɬɟɪɿ ɤɿɪɟɞɿ. Ɉɥɚɪ ɞԥɪɭɦɟɧɞɟɪ, ɦɚɤɪɨ- ɠԥɧɟ ɦɢɤɪɨɷɥɟ-
ɦɟɧɬɬɟɪ; ɿɲɟɤɬɟɝɿ ɬɿɪɿ ɦɢɤɪɨɚԑɡɚɥɚɪ, ɚɫ ԕɨɪɵɬɭ ɮɟɪɦɟɧɬɬɟɪɿ
ɠԥɧɟ ɬ.ɛ.
Ɇɚɤɪɨɧɭɬɪɢɟɧɬɬɟɪ
ɫɚɥɵɫɬɵɪɦɚɥɵ ɬԛɪɞɟ ɚɥԑɚɧɞɚ, ɤԧɩ
ɦԧɥɲɟɪɞɟ
ɬɚԑɚɦɧɵԙ ԕԝɪɚɦɵɧɞɚ ɛɨɥɚɞɵ ɠԥɧɟ ԕԝɪɵɥɵɦ ɛԧɥɿɤɬɟɪɿ
ɦɟɧ ɷɧɟɪɝɢɹɧɵԙ ɧɟɝɿɡɝɿ ɤԧɡɿ ɛɨɥɵɩ ɬɚɛɵɥɚɞɵ.