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S + 2ɇNɈ
3
(ɫԝɣɵɬ.)
o
ɇ
2
SɈ
4
+ 2NO
n
S + 6ɇNɈ
3
(ɤɨɧɰ.)
o
ɇ
2
SɈ
4
+ 6NɈ
2
n
+ 2ɇ
2
Ɉ
S + 2ɇ
2
SɈ
4
(ɤɨɧɰ.)
o
3SɈ
2
n
+ 2ɇ
2
Ɉ
3 Ɋ + 5ɇNɈ
3
(ɫԝɣɵɬ.) + ɇ
2
Ɉ
o
3ɇ
3
ɊɈ
4
+ 5NO
n
Ɋ + 5ɇNɈ
3
(ɤɨɧɰ.)
o
ɇɊɈ
3
+ 5NɈ
2
n
+ 2ɇ
2
Ɉ
2) ɇ
2
S, ɇȽ
Ωɪɟɤɟɬɬɟɫɭɿ
: ɛɟɣɦɟɬɚɥɥ ɫԥɣɤɟɫ ԕɵɲԕɵɥԑɚ ɞɟɣɿɧ,
ɚɥ ɇ
2
S – S -ɤɟ ɞɟɣɿɧ ɧɟɦɟɫɟ SɈ
2
n
– ɝɟ ɞɟɣɿɧ ɬɨɬɵԕɫɵɡɞɚɧɚɞɵ,
ɦԝɧɞɚԑɵ Ƚ - ɋ1
2
, ȼr
2
, I
2
(F
2
-ɞɚɧ ɛɚɫԕɚɫɵ).
ɇ
2
S + Ƚ
2
o
2ɇȽ + S
p
2ɇ
2
S + 3Ɉ
2
o
2ɇ
2
Ɉ + 2SɈ
2
n
2ɇ
2
S + Ɉ
2
(ɚɪɬ.)
o
2S
p
+ 2ɇ
2
Ɉ
3) ɛɟɥɫɟɧɞɿɥɿɝɿ ɠɨԑɚɪɵ ɝɚɥɨɝɟɧɞɟɪ ɇȽ ɬɢɩɬɿ ԕɵɲԕɵɥɞɚɪɞɚɧ
ɵԑɵɫɬɵɪɵɩ ɲɵԑɚɪɚɞɵ (ɇF-ɞɚɧ ɛɚɫԕɚɫɵ). F
2
o
ɋ1
2
o
ȼɝ
2
o
ȱ
2
ԕɚɬɚɪɞɚ ɛɟɥɫɟɧɞɿɥɿɝɿ ɬԧɦɟɧɞɟɣɞɿ:
2ɇȼr + ɋ1
2
o
2ɇɋȱ + ȼr
2
2HI + ɋȱ
2
o
2HCl + I
2
p
2HI + ȼr
2
o
2ɇȼr + I
2
p
x
ɧɟɝɿɡɞɟɪɦɟɧ Ωɪɟɤɟɬɬɟɫɭɿ:
ɫɿɥɬɿɥɟɪɦɟɧ ɬɟɤ ɤɟɣɛɿɪ
ɛɟɣɦɟɬɚɥɞɚɪ ԥɪɟɤɟɬɬɟɫɟɞɿ (Sɿ, S, Ɋ, F
2
, ɋl
2
, ȼr
2
, ȱ
2
):
Sɿ + 2ɄɈɇ + ɇ
2
Ɉ
o
Ʉ
2
SɿɈ
3
+ 2ɇ
2
n
3S + 6ɄɈɇ
o
2Ʉ
2
S + Ʉ
2
SɈ
3
+ 3ɇ
2
Ɉ
ɋ1
2
+ 2ɄɈɇ
o
Ʉɋ1 + ɄɋlO + ɇ
2
O
ɋ1
2
+ 6ɄɈɇ
o
5Ʉɋ1 + ɄC1Ɉ
3
+ 3ɇ
2
Ɉ
ɋ1
2
+ ɋɚ(Ɉɇ)
2
o
ɋɚɈɋ1
2
+ ɇ
2
Ɉ
2F
2
+ 2NɚɈɇ
o
2NɚF + ɈF
2
n
+ ɇ
2
Ɉ
4Ɋ + 3NɚɈɇ + 3ɇ
2
Ɉ
o
3Nɚɇ
2
ɊɈ
2
+ Ɋɇ
3
n
x
ɬΡɡɞɚɪɦɟɧ Ωɪɟɤɟɬɬɟɫɭɿ:
ɬԝɡɞɚɪɞɵԙ ɛɟɣɦɟɬɚɥɞɚɪɦɟɧ
ɛɚɪɥɵԕ ɪɟɚɤɰɢɹɫɵ – ɌɌɊ; ɛɟɥɫɟɧɞɿɥɿɝɿ ɠɨԑɚɪɵ ɝɚɥɨɝɟɧɞɟɪ
ɬԝɡɞɚɪɞɵԙ ɫɭɥɵ ɟɪɿɬɿɧɞɿɫɿɧɟɧ ɛɟɥɫɟɧɞɿɥɿɝɿ ɬԧɦɟɧɿɧ ɵԑɵɫɬɵɪɵɩ
ɲɵԑɚɪɚɞɵ (F
2
ɬԝɡɛɟɧ ɟɦɟɫ, ɬɟɤ ɇ
2
Ɉ
–
ɦɟɧ ԥɪɟɤɟɬɬɟɫɟɞɿ; ɫɭɫɵɡ
ɬԝɡɞɚɪ ɝɚɥɨɝɟɧɞɟɪɞɿ ɛɿɪ
-
ɛɿɪɿɧɟɧ ɵԑɵɫɬɵɪɵɩ ɲɵԑɚɪɦɚɣɞɵ:
2Fɟɋ1
2
+ ɋ1
2
o
2Fɟɋ1
3
Na
2
SɈ
3
+ S
o
Na
2
S
2
Ɉ
3